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She joined the PETA campaign Free Mali along with Xian Lim.
Chiu made a video plea for Mali, asking that she be moved to a sanctuary for the sake of her well being.
She garnered several acting awards for her portrayal of Audrey, a woman who is loved by two military men.
Aside from giving food and water, she also held week-long clothes auctions to raise money for Typhoon victims.
She played a woman who is cured from glomerulonephritis through a healer, but must suffer a curse.
From this film, she received a number of Best Supporting Actress nominations from almost all of the film award-giving bodies, missing only the Gawad Urian and The Young Critics' Circle.
She and her on-screen partner Gerald Anderson became regulars in ASAP XV and appeared together in several ABS-CBN shows Love Spell, comedy sitcom Aalog-Alog and in the film First Day High.
In 2007, Chiu starred in the primetime TV series entitled Sana Maulit Muli alongside Anderson which was released to significant acclaim.
Her other high-profile films include I Love You, Goodbye (2009) and Bakit Hindi Ka Crush Ng Crush Mo? She has received a PMPC Award for Best Drama Actress, four FAMAS Award nominations (winning one) and was hailed Princess of Philippine Movies and TV for her accomplishments in the film and television industry.